Yao-Jia Jiang PhD
AddTime: 2024-07-23 Hits: 11
Professor of Green Pesticide Synthesis
Doctoral Supervisor
State Key Laboratory of Green Pesticides
Contact details
Room-331, Phychemical Building-D, East Campus, Guizhou University
Email yjjiang@gzu.edu.cn
Phone (+86) 18795873973
Qualifications
BSc – Suzhou University, China 2007
MSc – Suzhou University, China 2010
PhD – Nanyang Technological University, Singapore 2015
Positions held
2023.12 - Present Professor, Guizhou University, Guiyang, China
2015.09 - 2023.11 Professor, Nanjing Tech University, Nanjing, China
Profile
Since 2015, Jiang has been dedicated to researching the pivotal scientific issue of the green and clean synthesis and structure-activity relationship of original pesticide molecules within the domain of green pesticide development. Employing the unsaturated bond skeletal editing strategy, he has devised an efficient catalytic synthesis system for transforming common bulk chemical raw materials such as olefins, alkynes, and their derivatives into high-value-added pesticide molecules and lead compounds. Jiang has synthesized a range of originally structured pesticide molecules, encompassing olefins, thiochromanones, and fluorine-containing heterocyclic derivatives. These pesticide compounds exhibit functionalities such as bacterial disease inhibition, plant virus suppression, and interruption of vector-borne disease transmission by insects, thereby paving the way for the emergence of novel green and clean pesticide formulations. Jiang's research accomplishments carry significance not only in theory but also in offering ground-breaking solutions for agricultural production. Jiang has published 34 papers as the first author/corresponding author in prestigious international journals, including J. Am. Chem. Soc., Angew. Chem., Ind. Ed., ACS Catal. and Chem. Sci. His contributions have garnered over 1000 citations in the SCI database, with his most cited paper receiving 190 citations. Additionally, Jiang has been granted 7 patents in China.
Selected recent publications (*corresponding author)
Y. Jiao, T. Wu, X. Zhang, Y. Jiang. (2024) Copper-catalyzed crosscoupling of vinyl nitrenes and CF3-carbenes to synthesize CF3-2-azadienes. Org. Chem. Front. 11. 67-73
Y. Li, J. Luo, Y. Jiang. (2023) C–F bond functionalizations via fluorinated carbenes. Org. Chem. Front. 10, 5782-5804
J. Han, Y. Liu, X. Yang, X. Zhang, Y. Zhu, M. Zhao, G. Hao,Y. Jiang. (2023) Stereoselective synthesis of 1,3- and 1,4-dicarbonyl-alkenes from cyclopropenes in a catalytic zinc system. Org. Chem. Front. 10, 4887-4894
K. Chen , J. Lv , J. Chen , J. Zhang, L. Li , M. Zhao, Y. Jiang. * (2023) Amine-Release Annulation of Enaminones: Bimetallic Co-Catalytic Synthesis of Cyclopentadienes from Alkynes. Org. Lett. 25, 4688-4693
X. Zhang, J. Zhang, J. Chen, B. Zhou, J. Zhang, S. Chen, J. Wu, * Y. Jiang. * (2023) Modular synthesis of fluorinated 2H-thiophenes via [4 + 1] cyclization of enaminothiones. Org. Biomol. Chem. 21, 3345-3349
J. Chen, J. Han, J. Zhang, L. Li, Z. Zhang, Y. Yang, Y. Jiang. * (2023) Rhodium/Amine Dual Catalytic System for Reassembling C≡C Bonds of Conjugated Alkynes with Cyclopropenes via Cutting/Insertion Cascade. ACS Catal. 12, 14748-14753
Y. Xu, L. Li, M. Zhao, Y. Jiang. * (2022) Reassembly of Unsaturated C–C Bonds by a Cutting/Insertion Cascade. Synlett. 33, A-H
F. Wang, R. Fu, J. Chen, J. Rong, E. Wang, J. Zhang, Z. Zhang, Y. Jiang. * (2022) Metal-free synthesis of gem-difluorinated heterocycles from enaminones and difluorocarbene precursors. Chem. Commun. 58, 3477-3480
R. Fu, Y. Liu, T. Wu, X. Zhang, Y. Zhu, J. Luo, Z. Zhang, Y. Jiang. * (2022) Metal-free synthesis of β-aminoketones by the reductive hydroamination of ynones. Chem. Commun. 58, 3525-3528
J. Chen, J. Han, T. Wu, J. Zhang, M. Li, Y. Xu, J. Zhang, Y. Jiao, Y. Yang, Y. Jiang. * (2022) Stereoselective cyclopropanation of enamides via C–C bond cleavage of cyclopropenes. Org. Chem. Front. 9, 1820-1825
C. Jiang, J. Wu, J. Han, K. Chen, Y. Qian, Z. Zhang, Y. Jiang. * (2021) An expedient synthesis of highly functionalized 1,3-dienes by employing cyclopropenes as C4 units. Chem. Commun. 57, 5710-5713
J. Wu, J. Zhang, Y. Jiao, G. Deng, Y. Li, Z. Zhang, * Y. Jiang. * (2021) Palladium-Catalyzed Decarbonylation of Amino Acid Derivatives via C–C Bond and C–N Bond Dual Activations. J. Org. Chem. 86, 17462-17470
P. Guo, W. Sun, Y. Liu, Y.-X. Li, T.-P. Loh, * Y. Jiang. * (2020) Stereoselective Synthesis of Vinylcyclopropa[b]indolines via a Rh-Migration Strategy. Org. Lett. 22, 5978-5983
J. Chen, M. Li, J. Zhang, W. Sun, * Y. Jiang. * (2020) Copper-Catalyzed Functionalization of Aza-Aromatic Rings with Fluoroalcohols via Direct C(sp2)–H/C(sp3)–H Coupling Reactions. Org. Lett. 22, 3033-3038
J. Rong, H. Li, R. Fu, W. Sun, T.-P. Loh, * Y. Jiang. * (2020) Cleavage and Reassembly C≡C Bonds of Ynones to Access Highly Functionalized Ketones. ACS Catal. 2020, 10, 3664-3669
Y. Chen, W. Yang, J. Wu, W. Sun, T.-P. Loh, * Y. Jiang. * (2020) 2H-Azirines as Potential Bifunctional Chemical Linkers of Cysteine Residues in Bioconjugate Technology. Org. Lett. 22, 2038-2043
X. Liang, P, Guo, W. Yang, M. Li, C. Jiang, W. Sun, T.-P. Loh, * Y. Jiang. * (2020) Stereoselective synthesis of trifluoromethyl-substituted 2H-furan-amines from enaminones. Chem. Commun. 56, 2043-2046
J. Chen, P, Guo, J, Zhang, J. Rong, W. Sun, Y. Jiang, * T.-P. Loh. * (2019) Synthesis of Functionalized α-Vinyl Aldehydes from Enaminones. Angew. Chem. Ind. Ed. 58, 12674-12679